Polymer Technology for Improved Oil Recovery (IOR)
One of the challenges in the production of oil and gas is that there is often a high rate of brine co-produced with the hydrocarbons from the reservoir. A common method to reduce this influx of undesirable water is to apply subsurface at these wells polymer solutions that will form gels or solids to block this water. Successful treatments will reduce the water rate, and thereby allow additional crude oil to be produced economically.
 
New polymers have been developed at PEER, which reduce this water influx, and extend this technology to high temperatures (to 200° C, or more), conditions where a standard polyacrylamide-chromium system can not be used. One novel polymer material (A, shown below) can form a visco-elastic plug, which increases greatly the resistance to water flow in our sand pack laboratory tests. Another new material (B, not shown) forms a highly viscous liquid/gel or solid precipitate that also have good thermal stability. Parameters that influence the kinetics have been evaluated, including chemical composition, temperature, and reservoir minerals.
Standard polyacrylamide-chromium
Novel thermally-stable polymer gel
Another, related application is to have a polymer-containing chemical system that can be added to the water injected into a reservoir to cause selective plugging in-depth. If designed correctly, the chemical system will "pop" and generate micro-particles at some distance from the water injection well. The net result to plug previously swept areas and force the injected water to invade portions of the reservoir rich in remaining crude oil lab tests in sand packs demonstrate how such a chemical system can create a "wave" of flow resistance (increased pressure)
PROJECTS:
Project 1: High temperature chemical systems for conformance control -- ChevronTexaco sponsor
 
Project 2: Diversion of injection water via polymers with selective plugging attributes -- Chevron Texaco sponsor