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GOR-Isotopes - A New Tool for the Quantitative Assessment of Gas Generation and Gas Typing in Petroleum Systems
GOR Isotopes
• What is “GOR Isotopes”?
A user-friendly, PC-based software package for modeling the kinetics of natural gas generation
• How is “GOR Isotopes” different from other gas geochemistry models?
GOR Isotopes is a forward predictive model of gas geochemistry based on kinetics theory (quantum chemistry) and laboratory experiments (pyrolysis) rather than an empirical model based on field observations
• What types of data does “GOR Isotopes” require?
GOR Isotopes requires some knowledge of the type of organic source rock and the thermal history of the basin
• What information can “GOR Isotopes” provide?
Depending on the level of detail of the input data, GOR Isotopes can predict:
Gas Yield Condensate Yield
Gas Source
Gas Composition
Thermal Maturity
Gas Migration History
Gas to Oil Ratio (GOR) Reservoir Filling History
Age of Gas Formation
Old Model of Natural Gas Generation
• Natural gas formation (Figure 2A):
Biogenic Gas - derived from bacterial degradation of organic matter
Primary Gas - generated during transformation of kerogen to oil
Secondary Gas - generated by cracking oil to gas
• Natural gas composition (chemical and isotopic) is produced by variable mixing of different end-members
• Natural gas compositions that do not appear to be simple mixtures can be explained by secondary alteration processes (e.g., biodegradation, migration related fractionation, etc.)
• Cross-plots of gas geochemistry show correlations that appear to support this model for specific fields or basins (Figure 2B)
• Empirical correlations derived from field data acquired from one basin can not be applied in other basins

Figure 2A: Simplistic Model of Natural Gas Generation

Figure 2B: Typical empirical cross-plots of natural gas geochemistry
A New Approach for Modeling Gas Geochemistry
• Despite the fact that gas formation is a more complex process than oil formation, the geochemical techniques currently employed for natural gas exploration are still relatively simplistic
• In contrast to oil which is generated in the so-called "thermal oil window", natural gas is generated throughout the entire thermal evolution of sedimentary basins (Figure 2C)
• The combination of kinetics theory with laboratory experimental data allows for the development of a more accurate model of natural gas generation
• This approach enables forward predictions to be made for specific basins based upon the source rock type and the thermal history of the basin
• Integration of kinetic model results into basin models provides a powerful tool for understanding natural gas formation, minimizing exploration risk, and maximizing realized gas resources
Figure 2C: Conceptual Model of Natural Gas Generation in Petroleum Systems